Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethyl 2-nitro-4-benzoylphenylacetate → Ethyl 2-amino-4-benzoylphenylacetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethyl 2-nitro-4-benzoylphenylacetate | HCID 13770535 | — |
| 촉매 | Nickel | HCID 935 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | Ethyl 2-amino-4-benzoylphenylacetate | HCID 13770537 | — |
반응 단계
To a solution of 14 g. (44.7 mmoles) of ethyl 2-nitro-4-benzoylphenylacetate in 225 ml. of ethanol was added 15 g. of wet Raney nickel and the mixture heated to reflux for 1.5 hours. The mixture was filtered and the filtrate concentrated to give a residual oil which was induced to crystallize by trituration with diethyl ether, 7.9 g., m.p. 150°-152° C.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04644005 |
| 출처 데이터셋 | uspto-grants-1987_02 |
| ORD ID | ord-1236173910b142118fc888e02d448121 |
| 출처 메모 | uspto-grants-1987_02 |