Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Benzaldehyde → N-[2-(diphenylphosphino)ethyl]-N-[phenylmethylene]amine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Benzaldehyde | HCID 240 | — |
| 반응물 | (2-Aminoethyl)diphenylphosphine | HCID 273264 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | N-[2-(diphenylphosphino)ethyl]-N-[phenylmethylene]amine | HCID 12145947 | 98% |
반응 단계
Under argon, a solution of 2-diphenylphosphino-ethylamine (590.3 mg, 2.57 mmol) and benzaldehyde (275.0 mg, 2.59 mmol) in ethanol (15 mL) was heated at 65° C. (oil bath) for 4 h. Then, the solvent was removed in-vacuo to give the desired product (>98% by 1H-NMR) as a colourless oil which solidified on standing (733.9 mg, 2.31 mmol, 90%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08692022B2 |
| 출처 데이터셋 | uspto-grants-2014_04 |
| ORD ID | ord-bce3ded93bba4133909b30d08d25708c |
| 출처 메모 | uspto-grants-2014_04 |