Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cyclohexanecarboxaldehyde → N-[cyclohexylmethylene]-N-[2-(diphenylphosphino)ethyl]amine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cyclohexanecarboxaldehyde | HCID 16275 | — |
| 반응물 | (2-Aminoethyl)diphenylphosphine | HCID 273264 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | N-[cyclohexylmethylene]-N-[2-(diphenylphosphino)ethyl]amine | HCID 59390144 | 98% |
반응 단계
Under argon, a solution of 2-diphenylphosphino-ethylamine (619.0 mg, 2.7 mmol) and cyclohexane carbaldehyde (306.2 mg, 2.73 mmol) in ethanol (15 mL) was heated at 65° C. (oil bath) for 4 h. Then, the solvent was removed in-vacuo to give the desired product (>98% by 1H-NMR) as a colourless liquid (880.5 mg, 2.7 mmol, quantitative).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08692022B2 |
| 출처 데이터셋 | uspto-grants-2014_04 |
| ORD ID | ord-f45b858d156f4ae0bec85f95b9f989d4 |
| 출처 메모 | uspto-grants-2014_04 |