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(S)-4-((2,6-dimethoxyphenoxy)methyl)-2,2-dimethyl-1,3-dioxolane → (R)-3-(2,6-Dimethoxyphenoxy)propane-1,2-diol

HRID 2366039
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HRID 2366039 반응식
[CH3:1][O:2][C:3]1[CH:17]=[CH:16][CH:15]=[C:14]([O:18][CH3:19])[C:4]=1[O:5][CH2:6][C@H:7]1[CH2:11][O:10]C(C)(C)[O:8]1>CO>[CH3:19][O:18][C:14]1[CH:15]=[CH:16][CH:17]=[C:3]([O:2][CH3:1])[C:4]=1[O:5][CH2:6][C@H:7]([OH:8])[CH2:11][OH:10]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

3

반응물 1

HCID 10849486(S)-4-((2,6-dimethoxyphenoxy)methyl)-2,2-dimethyl-1,3-dioxolane

생성물 1

HCID 10799347(R)-3-(2,6-Dimethoxyphenoxy)propane-1,2-diol수율 91.3%

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

A mixture of (S)-4-((2,6-dimethoxyphenoxy)methyl)-2,2-dimethyl-1,3-dioxolane (2.91 g, 10.85 mmol) and Amberlyst 15® (1.60 g) in methanol (30 ml) were stirred for 5 d. The mixture was filtered and evaporated to dryness to give 2.26 g of the title compound.

후처리

  1. filtrationThe mixture was filtered
  2. customevaporated to dryness

출처 및 근거

ORD 기록
ord-2b6f68e1adfb45508905cd02877fcd62
출처 데이터셋
uspto-grants-2014_04
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08697723B2

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