3,4-Dimethoxybenzeneacetonitrile → (2Z)-2-(3,4-dimethoxyphenyl)-3-[5-(3-nitrophenyl)furan-2-yl]prop-2-enenitrile

HRID 2366376

반응식

HRID 2366376 반응식
[N+:1]([C:4]1[CH:5]=[C:6]([C:10]2[O:16][C:13]([CH:14]=O)=[CH:12][CH:11]=2)[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2].[CH3:17][O:18][C:19]1[CH:20]=[C:21]([CH:25]=[CH:26][C:27]=1[O:28][CH3:29])[CH2:22][C:23]#[N:24]>>[CH3:17][O:18][C:19]1[CH:20]=[C:21](/[C:22](=[CH:14]/[C:13]2[O:16][C:10]([C:6]3[CH:7]=[CH:8][CH:9]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=3)=[CH:11][CH:12]=2)/[C:23]#[N:24])[CH:25]=[CH:26][C:27]=1[O:28][CH3:29]

참가 물질

3

반응물 2

HCID 667273,4-DimethoxybenzeneacetonitrileHCID 6124175-(3-Nitrophenyl)furfural

생성물 1

HCID 1179011(2Z)-2-(3,4-dimethoxyphenyl)-3-[5-(3-nitrophenyl)furan-2-yl]prop-2-enenitrile수율 98%

실험 절차

5-(3-Nitrophenyl)furfural (1.09 g) was condensed with 3,4-dimethoxybenzyl cyanide (889 mg) through Method A (production step 2), to thereby yield the target product (yield: 1.85 g, 98%).

출처 및 근거

ORD 기록
ord-d11d892ed4a4410cae26d359f4ddffc5
출처 데이터셋
uspto-grants-2014_04
특허 번호
US08697742B2

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