참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Ethylene | HCID 6325 | — |
| 반응물 | 2-Methylquinoline | HCID 7060 | — |
| 반응물 | Nitrobenzene | HCID 7416 | — |
| 생성물 | Aniline | HCID 6115 | 7.1% |
| 생성물 | Nitrobenzene | HCID 7416 | — |
반응 단계
Twenty grams of nitrobenzene and 1.1 grams of iodo (4-iodophenyl) bis(triphenylphosphine)-palladium was placed in a 300 ml. stainless steel rocking autoclave. This was sealed and pressurized with ethylene to 600 psi and heated to 160° C. This temperature was maintained for 17 hours. The autoclave was then cooled and vented. After opening the vessel the reaction mixture was analyzed by gas chromatography. This analysis showed that 6.8 grams of 2-methylquinoline (54.0% efficiency) was obtained together with 0.6 grams of aniline (7.1% efficiency) and 7 grams of unreacted nitrobenzene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04157445 |
|---|
| 출처 데이터셋 | uspto-grants-1979_06 |
|---|
| ORD ID | ord-aec30557fa214165851007ec1a03f945 |
|---|
| 출처 메모 | uspto-grants-1979_06 |
|---|
