참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Hydrochloric Acid | HCID 313 | — |
| 반응물 | Dichlorodiphenylsilane | HCID 6627 | — |
| 반응물 | Trichlorosilane | HCID 24811 | — |
| 반응물 | Diethyl aluminum chloride | HCID 16686102 | — |
| 생성물 | Chlorotrimethylsilane | HCID 6397 | — |
| 생성물 | 1,1',1''-(Chlorosilylidyne)tris(benzene) | HCID 6458 | — |
| 생성물 | Chlorodimethylphenylsilane | HCID 13029 | — |
| 생성물 | (Diphenylmethyl)chlorosilane | HCID 57361550 | — |
반응 단계
Into a 3-necked flask equipped with a stirrer, reflux condenser and a gas conduit, is introduced over a period of 5 minutes with constant agitation and at room temperature, 2-liters [measured at 20° C. and 720 mm Hg (abs.) and thus 0.94 percent based on the total weight of the silanes used], of gaseous hydrogen chloride, into a mixture consisting of 253 grams (1 mol) of diphenyldichlorosilane, 88 grams (1 mol) of tetramethylsilane, 3 grams of trichlorosilane and 3 grams diethylaluminum chloride. Stirring is continued for an additional 4 hours while the mixture is heated under reflux. Fractional distillation yields 30 grams of trimethylchlorosilane, 35 grams of phenyldimethylchlorosilane, 80 grams of diphenylmethylchlorosilane and 74 grams of triphenylchlorosilane.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04158010 |
|---|
| 출처 데이터셋 | uspto-grants-1979_06 |
|---|
| ORD ID | ord-88e552d6ce6545089f524dc47090fe0f |
|---|
| 출처 메모 | uspto-grants-1979_06 |
|---|
