Dimethoxymethane → 2,4,7,9-Tetraoxadecane

HRID 2371511노트

반응식

[CH3:1][O:2][CH2:3][O:4][CH3:5].[O:6]1[CH2:10][CH2:9][O:8][CH2:7]1>>[CH3:1][O:2][CH2:3][O:4][CH2:5][CH2:10][O:6][CH2:7][O:8][CH3:9]

참가 물질

반응물 2

HCID 8020Dimethoxymethane

HCID 125861,3-Dioxolane

생성물 1

HCID 109536902,4,7,9-Tetraoxadecane수율 50%

실험 절차

The reaction of 500 g dimethoxymethane (6.6 moles) with 100 g 1.3.dioxolane (1.4 moles), in the presence of an acidic catalyst, gave a mixture of unreacted dimethoxymethane, low molecular weight oligomers of 1,3.dioxolane and a product having the formula: CH3OCH2OCH2CH2OCH2OCH3 which was isolated in 50% yield. Fluorination of 80 g of the product in a 4 liter reactor containing 1.5 liters (CF2Cl)2CFOCF2OCF(CF2Cl)2 and 400 g sodium fluoride in an 18 hour reaction at 10° C., gave a 60% yield of perfluoro-2,4,7,9-tetraoxadecane (b.p. 79.0° C.).

출처 및 근거

ORD 기록: ord-30816ceca3b24d4ba6f4b211e023487f
출처 데이터셋: uspto-grants-1992_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05093432

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