methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate → rel-Methyl (1R,2S)-3-oxo-2-pentylcyclopentaneacetate

HRID 2378

반응식

HRID 2378 반응식
[OH:1][C@@H:2]1[CH2:6][CH2:5][C@H:4]([CH2:7][C:8]([O:10][CH3:11])=[O:9])[C@@H:3]1[CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>CO>[O:1]=[C:2]1[CH2:6][CH2:5][C@@H:4]([CH2:7][C:8]([O:10][CH3:11])=[O:9])[C@H:3]1[CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

참가 물질

3

반응물 1

HCID 7075801methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate

생성물 1

HCID 1738127rel-Methyl (1R,2S)-3-oxo-2-pentylcyclopentaneacetate

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate, characterized by a [α]20D superior to +17° (c=1.795 g/ 100 ml, methanol).

출처 및 근거

ORD 기록
ord-796c9df1b95145c8a5bab3faf51eb692
출처 데이터셋
uspto-grants-1998_03
특허 번호
US05728866

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