Hydrazine → Tridecanoic acid hydrazide

HRID 2380530노트

반응식

HRID 2380530 반응식
[C:1]([O:15]C)(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].[NH2:17][NH2:18]>C(O)C>[C:1]([NH:17][NH2:18])(=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

참가 물질

4

반응물 2

HCID 9321HydrazineHCID 15608Methyl tridecanoate

생성물 1

HCID 10823265Tridecanoic acid hydrazide

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

A solution of tridecanoic acid, methyl ester (24.63 g, 0.1078 mol), and anhydrous hydrazine (3.40 mL, 0.108 mol) in absolute ethanol (150 mL) was stirred at room temperature for 24 hours, then refluxed 2 days. The solution was allowed to cool, and the solid that crystallized was filtered off, washed, and dried in vacuo; yield 18.6 g (75%); mp 101°-104° C.

후처리

  1. temperaturerefluxed 2 days
  2. temperatureto cool
  3. customthe solid that crystallized
  4. filtrationwas filtered off
  5. washwashed
  6. customdried in vacuo

출처 및 근거

ORD 기록
ord-372b753926ac47e38a83d25bbc72ef98
출처 데이터셋
uspto-grants-1994_11
특허 번호
US05366987

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