Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Cumene → 2-Phenyl-2-propanol
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Cumene | HCID 7406 | — |
| 반응물 | N-Hydroxyphthalimide | HCID 10665 | — |
| 생성물 | Phenol | HCID 996 | 10.4% |
| 생성물 | Cumene | HCID 7406 | — |
| 생성물 | Acetophenone | HCID 7410 | — |
| 생성물 | 2-Phenyl-2-propanol | HCID 12053 | 13.1% |
반응 단계
0.3 mmol of N-hydroxyphthalimide and 0.3 mmol of Co(II) acetate are added at a temperature of 125° C. to 30 mmol of cumene in a round-bottomed flask having an attached reflux condenser. The reaction mixture is stirred for 8 hours at said temperature under an oxygen atmosphere of 1 bar. Not the target product, but acetophenone is obtained at a selectivity of 58.7%, 2-phenyl-2-propanol (13.1%) and phenol (10.4%) at a cumene conversion rate of 49.3%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06852893B2 |
| 출처 데이터셋 | uspto-grants-2005_02 |
| ORD ID | ord-2c65b7ac54fc4b36890f2034db340da0 |
| 출처 메모 | uspto-grants-2005_02 |