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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 23865생성일: 2026년 10월 24일

Isopropanol → n-(2-Hydroxyethyl)ammonium methyl sulfate

https://huagongshe.com/ko/reaction/23865

반응식

참여 물질

역할이름HCID투입량
반응물IsopropanolHCID 3776—
반응물Dimethyl SulfateHCID 6497—
반응물TriethanolamineHCID 7618—
용매1-PropanolHCID 1031—
생성물n-(2-Hydroxyethyl)ammonium methyl sulfateHCID 22035489—

반응 단계

Triethanol amine (149 g) and 547 g of hydrogenated tallow fatty acid were used and subjected to an esterification reaction at 200° C. under nitrogen atmosphere for 10 hours, and to this was added 139 g of isopropanol, and this was subjected to a quaternizing reaction at 60° C. by using 126 g of dimethyl sulfate to obtain a propanol solution of N-methyl-N,N-bis(hydrogenated tallow alkanoyl oxyethyl)-N-(2-hydroxyethyl)ammonium methyl sulfate. It was found through NMR measurements that this solution had a long-chain alkyl quaternary ammonium salt content of 12%, a di-long-chain alkyl quaternary ammonium salt content of 35% and mono-long-chain alkyl quaternary ammonium salt content of 15%. The resulting isopropanol solution was taken in a manner so as to set the total amount of quaternary ammonium salt to 5 g, and this was mixed with 2 g of ethyleneoxide 12 mole adduct (HLB=14.0) of hydrogenated tallow fatty acid methyl ester, in the same manner as Example 1 to prepare 100 g of softener composition.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US06855682B2
출처 데이터셋uspto-grants-2005_02
ORD IDord-da1ff4e09f8e4a52ba3403d8ddb3a3e3
출처 메모uspto-grants-2005_02