Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Thiophenol → 5-Chloro-2-pyridinyl phenyl sulfide
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Thiophenol | HCID 7969 | — |
| 반응물 | 2,5-Dichloropyridine | HCID 27685 | — |
| 생성물 | 5-Chloro-2-pyridinyl phenyl sulfide | HCID 12133078 | 60.6% |
반응 단계
2,5 Dichloropyridine (8.9 g, 60 mmol) and thiophenol (6.1 mL, 60 mmol) were heated to 150° C. for 41 h. The mixture then was removed from heat and cooled to room temperature. Column chromatography (silica gel, 200 mL) using hexanes as eluent gave 8.06 g of the title compound; IR (liq.) 1564, 1548, 1476, 1440, 1356, 1122, 1092, 1024, 1006, 821, 748, 727, 706, 691, 628 cm−1. 1H NMR (CDCl3) δ 6.8, 7.4, 7.6, 8.38.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06855709B2 |
| 출처 데이터셋 | uspto-grants-2005_02 |
| ORD ID | ord-abb631e1a8394b2ab868383dd7c1e0d7 |
| 출처 메모 | uspto-grants-2005_02 |