Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Water → BIS-(beta-M-CHLOROBENZAMIDOETHYL)SULFIDE
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Water | HCID 962 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | Benzoyl chloride, 3-chloro- | HCID 69252 | — |
| 반응물 | 2,2'-Thiobis(ethanamine) | HCID 70096 | — |
| 용매 | Diethyl Ether | HCID 3283 | — |
| 생성물 | BIS-(beta-M-CHLOROBENZAMIDOETHYL)SULFIDE | HCID 22749424 | — |
반응 단계
To a solution of bis-(β-aminoethyl)sulfide (2.5 g., 0.021 M) and sodium hydroxide (1.6 g., 0.04 M) in 20 ml. of water and 40 ml. of ether was added a solution of m-chlorobenzoyl chloride (7.0 g., 0.04 M) in 15 ml. of ether at 10°-20° C. A precipitate appeared. The mixture was stirred 45 minutes at room temperature and the solid filtered, washed with water and dried. The product was a white solid. m.p. 150°-152° C. Its structure was confirmed by IR spectroscopy. Yield: 7.0 g. (88%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04021228 |
| 출처 데이터셋 | uspto-grants-1977_05 |
| ORD ID | ord-7f583b4b5f8842d4914740115c99b2ee |
| 출처 메모 | uspto-grants-1977_05 |