1-Octanol → Octyl 2-aminobenzoate

HRID 2397269노트

반응식

HRID 2397269 반응식
C[O-].[Na+].[C:4]([O:13][CH3:14])(=[O:12])[C:5]1[C:6](=[CH:8][CH:9]=[CH:10][CH:11]=1)[NH2:7].[CH2:15](O)[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21]C>CO>[C:4]([O:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])(=[O:12])[C:5]1[C:6](=[CH:8][CH:9]=[CH:10][CH:11]=1)[NH2:7]

참가 물질

5

반응물 3

HCID 9571-OctanolHCID 8635Methyl AnthranilateHCID 10942334Sodium Methoxide

생성물 1

HCID 12590944Octyl 2-aminobenzoate

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

To a methanolic solution of sodium methoxide (prepared from 30 ml of methanol and 0.2 g. of sodium) were added 91 g. of methyl anthranilate and 78 g. of 1-octanol. The reaction mixture was heated at 90° C. for 0.75 hour and at 125° C. for 0.75 hour while methanol was removed by distillation. The residue was washed with water, dried, and distilled. n-Octyl anthranilate was obtained as a clear liquid, b.p. 139°-144° C. at about 0.5 mm.

후처리

  1. customwas removed by distillation
  2. washThe residue was washed with water
  3. customdried
  4. distillationdistilled

출처 및 근거

ORD 기록
ord-1768970577744967b1bb9b803ddf9550
출처 데이터셋
uspto-grants-1977_05
특허 번호
US04021470

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