Benzoic acid, 2,4,6-triiodo- → HCID 21438011, 화합물

HRID 2397355노트

반응식

HRID 2397355 반응식
[I:1][C:2]1[CH:10]=[C:9]([I:11])[CH:8]=[C:7]([I:12])[C:3]=1[C:4](O)=[O:5].S(Cl)([Cl:15])=O>>[I:1][C:2]1[CH:10]=[C:9]([I:11])[CH:8]=[C:7]([I:12])[C:3]=1[C:4]([Cl:15])=[O:5]

참가 물질

3

반응물 2

HCID 16196Benzoic acid, 2,4,6-triiodo-HCID 24386Thionyl Chloride

생성물 1

HCID 21438011HCID 21438011, 화합물

실험 절차

2,4,6-Triiodobenzoic acid (15 g) was suspended in thionyl chloride (75 ml) was refluxed. Thirty minutes after the starting material was dissolved, the reaction solution was cooled and evaporated in vacuo. The residue was dissolved in hot benzene (40 ml), cooled to room temperature, filtered and the filtrate evaporated in vacuo. Yield: 13.6 g. I.R. (KBr): 1785 cm -1 (--COCl).

후처리

  1. temperaturewas refluxed
  2. dissolutionThirty minutes after the starting material was dissolved
  3. temperaturethe reaction solution was cooled
  4. customevaporated in vacuo
  5. dissolutionThe residue was dissolved in hot benzene (40 ml)
  6. filtrationfiltered
  7. customthe filtrate evaporated in vacuo

출처 및 근거

ORD 기록
ord-a84b296a68a84936a1d4bf1a861bfb06
출처 데이터셋
uspto-grants-1977_05
특허 번호
US04021481

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