4-Chloro-1,2-diaminobenzene → 11-Chlorodibenzo[a,c]phenazine

반응식

[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([NH2:8])=[C:4]([NH2:9])[CH:3]=1.[C:10]1(=O)[C:23]2[CH:22]=[CH:21][C:20]3[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=3)[C:14]=2[CH:13]=[CH:12][C:11]1=O>>[Cl:1][C:2]1[CH:3]=[C:4]2[C:5](=[CH:6][CH:7]=1)[N:8]=[C:22]1[C:21]([C:20]3[CH:19]=[CH:18][CH:17]=[CH:16][C:15]=3[C:14]3[CH:13]=[CH:12][CH:11]=[CH:10][C:23]=31)=[N:9]2

참가 물질

반응물 2

HCID 72634-Chloro-1,2-diaminobenzene

HCID 30805661,2-Phenanthrenedione

생성물 1

HCID 62880011-Chlorodibenzo[a,c]phenazine수율 83%

실험 절차

When one tenth mole each of 4-chloro-o-phenylendiamine and phenanthrenequinone were reacted by the method of Example 7(A), 26 g. (83 percent yield) of 11-chlorodibenzo[a,c]phenazine, mp = 241-242° C. were obtained.

출처 및 근거

ORD 기록: ord-df44fd8416514c42b9b0db750c31feca
출처 데이터셋: uspto-grants-1977_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04024142

반응 노트

불러오는 중…