Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethylene → 1-Decene
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethylene | HCID 6325 | — |
| 반응물 | 1-Octene | HCID 8125 | — |
| 반응물 | Palmitoleic Acid | HCID 445638 | — |
| 반응물 | Oleic Acid | HCID 445639 | — |
| 반응물 | Methyl 9-decenoate | HCID 1778877 | — |
| 생성물 | 1-Decene | HCID 13381 | — |
| 생성물 | Ethyl 9-decenoate | HCID 522255 | — |
반응 단계
Ethenolysis comprises a cross-metathesis reaction involving ethene. According to some preferred embodiments of the invention, a mixture of ethyl esters of Palmitoleic acid (C16:1) and Oleic acid (C18:1) are subjected to conditions of ethenolysis to yield a mixture of α-olefins (1-Octene and 1-Decene) and Methyl 9-Decenoate. See FIG. 8. The 1-Octene is a product unique to ethenolysis of Palmitoleic acid (C16:1). In the inventive method, Ethyl 9-Decenoate and 1-Decene will also form from the mixture of Palmitoleic and Oleic acid ethyl esters. Prior art methods using Oleic acid esters (Methyl Oleate) as the starting material only produce Methyl 9-Decenoate and 1-Decene.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08642814B1 |
| 출처 데이터셋 | uspto-grants-2014_02 |
| ORD ID | ord-d007832479fa493b91ab0a957c152e6b |
| 출처 메모 | uspto-grants-2014_02 |