HCID 9250987, 화합물 → HCID 16080835, 화합물

HRID 2399278노트

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HRID 2399278 반응식
[N+:1]([C:4]1[CH:20]=[CH:19][CH:18]=[CH:17][C:5]=1[O:6][C:7]1[CH:16]=[CH:15][CH:14]=[CH:13][C:8]=1[C:9]([O:11][CH3:12])=[O:10])([O-])=O>C(OCC)(=O)C.[Pd]>[NH2:1][C:4]1[CH:20]=[CH:19][CH:18]=[CH:17][C:5]=1[O:6][C:7]1[CH:16]=[CH:15][CH:14]=[CH:13][C:8]=1[C:9]([O:11][CH3:12])=[O:10]

참가 물질

4

반응물 1

HCID 9250987HCID 9250987, 화합물

생성물 1

HCID 16080835HCID 16080835, 화합물

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 8857Ethyl Acetate용매

실험 절차

Methyl 2-(2-nitrophenoxy)benzoate (540 mg, 0.00198 mol) was dissolved in ethyl acetate (20 mL) and palladium on carbon catalyst (270 mg) was added. The mixture was hydrogenated at 57 psi for 2 h. The catalyst was filtered and the solvents were evaporated to yield the title compound. 1H NMR (250 MHz, CDCl3) δ7.83 (dd, 1H), 7.41 (m, 1H), 7.10 (m, 1H), 6.97 (m, 2H), 6.82 (m, 2H), 6.69 (m, 1H).

후처리

  1. filtrationThe catalyst was filtered
  2. customthe solvents were evaporated

출처 및 근거

ORD 기록
ord-3aaeb6604fbb4331ac8a03762779fca0
출처 데이터셋
uspto-grants-1995_09
특허 번호
US05447957

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