2-Diazonio-3-oxoprop-1-en-1-olate → HCID 86628158, 화합물

반응식

[N+:1](=[C:3](C=O)[CH:4]=O)=[N-:2].[Cl-].[CH3:9][O:10][C:11]1[CH:12]=[C:13]([CH:15]=[CH:16][C:17]=1[O:18][CH3:19])[NH2:14]>>[CH3:9][O:10][C:11]1[CH:12]=[C:13]([N:14]2[CH:4]=[CH:3][N:1]=[N:2]2)[CH:15]=[CH:16][C:17]=1[O:18][CH3:19]

참가 물질

반응물 2

HCID 537954722-Diazonio-3-oxoprop-1-en-1-olate

HCID 86628159HCID 86628159, 화합물

생성물 1

HCID 86628158HCID 86628158, 화합물

실험 절차

The derivative (114m) was prepared with 80.0% of output, as of the reaction of diazomalonaldehyde with the 3,4-dimethoxyaniline chloride, thus obtaining an amorphous yellow solid with fusion point at 170.0-171.0° C.

후처리

customthus obtaining an amorphous yellow solid with fusion point at 170.0-171.0° C.

출처 및 근거

ORD 기록: ord-38545452e19447aba639f85444ae7f8b
출처 데이터셋: uspto-grants-2014_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08796316B2

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