3-Acetylpyridine → 3-PYRIDINEACETALDEHYDE, ALPHA-OXO-

반응식

[Se](=O)=[O:2].[C:4]([C:7]1[CH:8]=[N:9][CH:10]=[CH:11][CH:12]=1)(=[O:6])[CH3:5]>>[N:9]1[CH:10]=[CH:11][CH:12]=[C:7]([C:4]([CH:5]=[O:2])=[O:6])[CH:8]=1

참가 물질

반응물 2

HCID 95893-Acetylpyridine

HCID 24007Selenium Dioxide

생성물 1

HCID 102360083-PYRIDINEACETALDEHYDE, ALPHA-OXO-수율 90.3%

실험 절차

3-Pyridylglyoxal (5.0 g, crude) was prepared from selenium dioxide (6.82 g, 61.4 mmol) and 3-acetyl pyridine (5.0 g, 41.0 mmol) according to the typical procedure used for Preparation 1.

후처리

customused for Preparation 1

출처 및 근거

ORD 기록: ord-5a9319c65e374ddaa6e6fbac48c3e394
출처 데이터셋: uspto-grants-2014_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08809525B2

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