Aniline → 6-(Phenylamino)-5,8-quinolinedione

HRID 2412431노트

반응식

HRID 2412431 반응식
[N:1]1[C:10]2[C:9](=[O:11])[CH:8]=[CH:7][C:6](=[O:12])[C:5]=2[CH:4]=[CH:3][CH:2]=1.[NH2:13][C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1.[Cl-].[Ce+3].[Cl-].[Cl-]>C(O)C>[NH:13]([C:7]1[C:6](=[O:12])[C:5]2[CH:4]=[CH:3][CH:2]=[N:1][C:10]=2[C:9](=[O:11])[CH:8]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1

참가 물질

5

반응물 3

HCID 6115AnilineHCID 24636Cerium(III) chlorideHCID 3883065,8-Dihydroquinoline-5,8-dione

생성물 1

HCID 39766-(Phenylamino)-5,8-quinolinedione

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

Twenty and one-half grams of quinoline-5,8-quinone were dissolved in 500 ml of absolute ethanol, then 13 g of aniline were added, followed by the addition of 32 g of cerium chloride. This reaction mixture was refluxed overnight. The resulting mixture had a brown-blue color and was stirred and then left to cool to room temperature for about 26 hours.

후처리

  1. temperatureThis reaction mixture was refluxed overnight
  2. waitleft

출처 및 근거

ORD 기록
ord-0282439f41104f159b40942a981c5397
출처 데이터셋
uspto-grants-1985_01
특허 번호
US04492704

반응 노트

불러오는 중…