Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Carbonate → 9-Decenyl bis(pentafluoroethyl)phosphinite
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Carbonate | HCID 11430 | — |
| 반응물 | 9-Decen-1-ol | HCID 25612 | — |
| 반응물 | Bis(pentafluoroethyl)phosphinous chloride | HCID 2757428 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | 9-Decenyl bis(pentafluoroethyl)phosphinite | HCID 86653814 | — |
반응 단계
0.31 g (1.9 mmol) of 9-decen-1-ol is initially introduced in CH2Cl2 with excess K2CO3, and 0.64 g (2.1 mmol) of bis(pentafluoroethyl)phosphinous acid chloride, (C2F5)2PCl, is condensed in. After the mixture has been stirred at room temperature for 30 minutes, the precipitate is filtered off, and volatile substances are removed in vacuo. The product, 9-decenyl bis(pentafluoroethyl)phosphinite, remains as a colourless, oily liquid, which is characterised by spectroscopy.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08648202B2 |
| 출처 데이터셋 | uspto-grants-2014_02 |
| ORD ID | ord-c98278044eb643478b8fe43038cd321c |
| 출처 메모 | uspto-grants-2014_02 |