Methyl p-toluenesulfonate → HCID 20430720, 화합물
반응식
[C:1]1([Sb:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:20]1([CH3:31])[CH:25]=[CH:24][C:23]([S:26]([O:29]C)(=[O:28])=[O:27])=[CH:22][CH:21]=1>>[C:20]1([CH3:31])[CH:21]=[CH:22][C:23]([S:26]([O-:29])(=[O:27])=[O:28])=[CH:24][CH:25]=1.[CH3:20][Sb+:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1참가 물질
3
반응 조건
- 온도
- 130 °C
실험 절차
A mixture of 17.65 g (0.05 mol) of triphenylstibine and 9.31 g (0.05 mol) of methyl p-toluenesulfonate was heated in a 130° C. bath with nitrogen bubbling through the melt for 18 hr. The resulting syrup was cooled to an amorphous glass which was crystallized by treatment with ether. The resultant crystals were collected and dried.
후처리
- temperatureThe resulting syrup was cooled to an amorphous glass which
- customwas crystallized by treatment with ether
- customThe resultant crystals were collected