Sodium Methoxide → HCID 54496620, 화합물

HRID 2413449노트

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HRID 2413449 반응식
C[O-].[Na+].[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[CH:16]=O>CO.C(O)C>[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[CH:16]=[CH:16][C:9]1[C:10]([Cl:15])=[CH:11][CH:12]=[C:13]2[C:8]=1[N:7]=[CH:6][C:5]([Cl:4])=[CH:14]2

참가 물질

5

반응물 2

HCID 10942334Sodium MethoxideHCID 13090787HCID 13090787, 화합물

생성물 1

HCID 54496620HCID 54496620, 화합물

시약·촉매·용매 2

HCID 702Ethanol용매HCID 887Methanol용매

실험 절차

18 ml of a 15% strength solution of sodium methylate in methanol were added dropwise, at room temperature, to a suspension of 25.4 g of 3,7-dichloro-8-triphenylphosphoniummethylquinoline chloride and 11.3 g of 3,7-dichloro-8-formylquinoline in 150 ml of ethanol. The mixture was stirred for 2 hours, after which the yellow precipitate was filtered off under suction, treated with water and again filtered off under suction.

후처리

  1. filtrationafter which the yellow precipitate was filtered off under suction
  2. additiontreated with water
  3. filtrationagain filtered off under suction

출처 및 근거

ORD 기록
ord-8841b6b409c7485da9c83fc3053ea8a7
출처 데이터셋
uspto-grants-1988_01
특허 번호
US04717416

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