(Ethoxycarbonylmethyl)triphenylphosphonium → HCID 53853771, 화합물

HRID 2413450노트

반응식

HRID 2413450 반응식
C[O-].[Na+].[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[CH:16]=[O:17].[CH2:18]([O:20][C:21]([CH2:23][P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)=O)[CH3:19]>CO.C(O)C>[Cl:4][C:5]1[CH:6]=[N:7][C:8]2[C:13]([CH:14]=1)=[CH:12][CH:11]=[C:10]([Cl:15])[C:9]=2[C:16](=[O:17])[CH:19]=[CH:18][O:20][CH2:21][CH3:23]

참가 물질

6

반응물 3

HCID 73732(Ethoxycarbonylmethyl)triphenylphosphoniumHCID 10942334Sodium MethoxideHCID 13090787HCID 13090787, 화합물

생성물 1

HCID 53853771HCID 53853771, 화합물

시약·촉매·용매 2

HCID 702Ethanol용매HCID 887Methanol용매

실험 절차

36 ml of a 15% strength solution of sodium methylate in methanol were added dropwise, at 20° C., to a suspension of 22.6 g of 3,7-dichloro-8-formylquinoline and 38.4 g of ethoxycarbonylmethyl-triphenyl-phosphonium chloide in 200 ml of ethanol. The mixture was stirred for 3 hours, after which the precipitate was filtered off under suction, washed with water and dried.

후처리

  1. filtrationafter which the precipitate was filtered off under suction
  2. washwashed with water
  3. customdried

출처 및 근거

ORD 기록
ord-0601905ab212409aaa373c77feecf319
출처 데이터셋
uspto-grants-1988_01
특허 번호
US04717416

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