Trioctyl phosphate → Trioctyl phosphate 2,6,10,14-tetramethylpentadecane

HRID 2413463

반응식

HRID 2413463 반응식
[P:1]([O:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])([O:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])=[O:2].[CH3:30][CH:31]([CH2:33][CH2:34][CH2:35][CH:36]([CH3:48])[CH2:37][CH2:38][CH2:39][CH:40]([CH3:47])[CH2:41][CH2:42][CH2:43][CH:44]([CH3:46])[CH3:45])[CH3:32].C(OS([O-])(=O)=O)CCCCCCCCCCC.[Na+]>C(O)C>[P:1]([O:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])([O:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29])([O:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[O:2].[CH3:46][CH:44]([CH2:43][CH2:42][CH2:41][CH:40]([CH3:47])[CH2:39][CH2:38][CH2:37][CH:36]([CH3:48])[CH2:35][CH2:34][CH2:33][CH:31]([CH3:32])[CH3:30])[CH3:45]

참가 물질

5

반응물 3

HCID 15733Trioctyl phosphateHCID 15979PristaneHCID 3423265Sodium Lauryl Sulfate

생성물 1

HCID 86741959Trioctyl phosphate 2,6,10,14-tetramethylpentadecane

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

In 100 ml of an aqueous solution containing 20% by volume of ethanol were incorporated 100 ml of a mixed liquid comprising trioctyl phosphate and 2,6,10,14-tetramethylpentadecane at a weight ratio of 2:1 and 0.2 g of sodium laurylsulfate, and ultrasonic vibration having a frequency of 28 KHz was applied to the liquid mixture for 2 minutes to form an emulsion in which particles of the trioctyl phosphate/2,6,10,14-tetramethylpentadecane mixed liquid having an average particle diameter of 0.3 μm were dispersed in the aqueous solution of ethanol. The emulsion was filtered at a potential gradient of 4.5 V/cm under a pressure of 0.01 kg/cm2 through a polytetrafluoroethylene porous membrane having a nominal average pore size of 2.0 μm. Only the phase of trioctyl phosphate/2,6,10,14-tetramethylpentadecane dispersed in the form of particles permeated through the membrane at a flow rate of 48 kg/m2.hr, and the permeated liquid formed a continuous phase.

출처 및 근거

ORD 기록
ord-8d0783b5367c4104a7d27d8026384aeb
출처 데이터셋
uspto-grants-1988_01
특허 번호
US04717480

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