HCID 21276215, 화합물 → (10-Bromo-1-anthracenyl)methanol

HRID 2413614노트

반응식

HRID 2413614 반응식
[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[C:16](O)=[O:17]>C1COCC1>[Br:1][C:2]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH:9]=[C:8]2[C:3]=1[CH:4]=[CH:5][CH:6]=[C:7]2[CH2:16][OH:17]

참가 물질

3

반응물 1

HCID 21276215HCID 21276215, 화합물

생성물 1

HCID 13375398(10-Bromo-1-anthracenyl)methanol

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

10-Bromo-1-anthracenecarboxylic acid made from example 2B by the procedure of E. Barnett, J. W. Cook, and H. H. Grainger, Ber. 57 B, 1775 (1924), was reduced with BH3 in THF by the procedure outlined in 2C to give (10-bromo-1-anthryl)methanol mp 125°-127°, (EtOAc/hexane), (C,H,Br).

출처 및 근거

ORD 기록
ord-862fc819030042d3a249162fcf342e6d
출처 데이터셋
uspto-grants-1988_01
특허 번호
US04719047

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