Ethanol → 10-Ethoxy-9-anthracenecarbaldehyde

HRID 2413646

반응식

HRID 2413646 반응식
[CH3:1][O:2][C:3]1[C:16]2[C:11](=[CH:12][CH:13]=[CH:14][CH:15]=2)[C:10]([CH:17]=[O:18])=[C:9]2[C:4]=1[CH:5]=[CH:6][CH:7]=[CH:8]2.[CH3:19]C[O-].[Na+].CCO.ClC1C2C(=CC=CC=2)C(C=O)=C2C=1C=CC=C2>C(Cl)Cl.CCCCCC>[CH2:1]([O:2][C:3]1[C:4]2[C:9](=[CH:8][CH:7]=[CH:6][CH:5]=2)[C:10]([CH:17]=[O:18])=[C:11]2[C:16]=1[CH:15]=[CH:14][CH:13]=[CH:12]2)[CH3:19]

참가 물질

6

반응물 4

HCID 702EthanolHCID 8270310-Chloro-9-anthraldehydeHCID 2723922Sodium ethoxideHCID 1309004410-Methoxyanthracene-9-carbaldehyde

생성물 1

HCID 1337540410-Ethoxy-9-anthracenecarbaldehyde

시약·촉매·용매 1

HCID 21226440Methylenechloride Hexane용매

실험 절차

Using the procedure outlined in 13A, except that NaOEt (Aldrich)/EtOH was used instead of NaOCH3 /CH3OH, 10-chloro-9-anthraldehyde (Aldrich) gave 10-ethoxy-9-anthracenecarbaldehyde mp 88°-90°, (CH2Cl2 /hexane) (C, H).

출처 및 근거

ORD 기록
ord-2c6e808804a3410cb68d14e085eb99f3
출처 데이터셋
uspto-grants-1988_01
특허 번호
US04719049

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