Sodium Iodide → Phosphinic acid, P-phenyl-P-(2,4,6-trimethylbenzoyl)-, sodium salt (1:1)

HRID 2413829노트

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HRID 2413829 반응식
[CH3:1][C:2]1[CH:19]=[C:18]([CH3:20])[CH:17]=[C:16]([CH3:21])[C:3]=1[C:4]([P:6]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:9])[O:7]C)=[O:5].[I-].[Na+:23]>C(C(C)=O)C>[CH3:1][C:2]1[CH:19]=[C:18]([CH3:20])[CH:17]=[C:16]([CH3:21])[C:3]=1[C:4]([P:6]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)(=[O:7])[O-:9])=[O:5].[Na+:23]

참가 물질

4

반응물 2

HCID 5238Sodium IodideHCID 20501383Methyl phenyl(2,4,6-trimethylbenzoyl)phosphinate

생성물 1

HCID 23690966Phosphinic acid, P-phenyl-P-(2,4,6-trimethylbenzoyl)-, sodium salt (1:1)

시약·촉매·용매 1

HCID 6569Methyl Ethyl Ketone용매

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온도
55 °C

실험 절차

60.5 parts by weight of methyl 2,4,6-trimethylbenzoylphenylphosphinate (as described in U.S. Pat. No. 4,265,723) and 33 parts by weight of sodium iodide were dissolved in 560 parts by volume of methyl ethyl ketone, and the solution was stirred for 2.5 hours at 55° C. The resulting precipitate was filtered off, washed with methyl ethyl ketone and dried, the desired product being obtained.

후처리

  1. filtrationThe resulting precipitate was filtered off
  2. washwashed with methyl ethyl ketone
  3. customdried

출처 및 근거

ORD 기록
ord-a1a7ab26b1ce44cf9d62448b84b59e81
출처 데이터셋
uspto-grants-1988_01
특허 번호
US04719297

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