Sodium Iodide → HCID 22636917, 화합물

반응식

[CH3:1][Sn:2]([CH3:11])([CH3:10])[C:3]1[S:7][C:6]([CH2:8][OH:9])=[CH:5][CH:4]=1.[I-].[Na+].Cl[CH2:15][C:16]([N:18]1[CH2:23][CH2:22][S:21][CH2:20][CH2:19]1)=[O:17]>>[N:18]1([C:16](=[O:17])[CH2:15][O:9][CH2:8][C:6]2[S:7][C:3]([Sn:2]([CH3:11])([CH3:10])[CH3:1])=[CH:4][CH:5]=2)[CH2:23][CH2:22][S:21][CH2:20][CH2:19]1

참가 물질

반응물 3

HCID 5238Sodium Iodide

HCID 189186374-(2-Chloroacetyl) thiomorpholine

HCID 22636973HCID 22636973, 화합물

생성물 1

HCID 22636917HCID 22636917, 화합물

실험 절차

The 1-thiomorpholin-4-yl-2-(5-trimethylstannanyl-thiophen-2-ylmethoxy)-ethanone employed is prepared analogously to example (3a) (stage b)) starting from (5-trimethylstannanyl-thiophen-2-yl)-methanol (7.66 g; 27.67 mmol; described, in example (3a), stage a)), sodium iodide (4.07 g; 27.34 mmol) and 2-chloro-1-thiomorpholiri-4-yl-ethanone (5.92 g; 32.94 mmol)

출처 및 근거

ORD 기록: ord-681e745c06394b75adb880faeba41a1c
출처 데이터셋: uspto-grants-2004_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06821980B1

반응 노트

불러오는 중…