돌아가기
Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 2417012생성일: 2026년 10월 27일

Trimethylolpropane → Urethane acrylate

https://huagongshe.com/reaction/2417012

반응식

참여 물질

역할이름HCID투입량
반응물TrimethylolpropaneHCID 6510—
반응물Stearyl AlcoholHCID 8221—
반응물4-MethoxyphenolHCID 9015—
반응물1,3-Bis(isocyanatomethyl)benzeneHCID 19262—
반응물Bis(isocyanatomethyl)benzeneHCID 3035160—
반응물Di-n-butyldilauryltinHCID 9809426—
용매TolueneHCID 1140—
생성물Urethane acrylateHCID 21863578—

반응 조건

온도40 °C

반응 단계

Into a flask similar to the flask in Synthesis Example 1 were charged 44.8 parts of toluene and 4.6 parts of stearyl alcohol (NAA-46), followed by heating of the mixture to 40° C. After the confirmation of thorough dissolution of stearyl alcohol, 50 parts of xylylene diisocyanate subjected to trimethylol-propane adduct modification (“TAKENATE D-110N” a trade name of Takeda Chemical Industries, Ltd., N.V.: 75, NCO %: 11.5) were charged and the mixture was heated to 70° C. After 30 minutes of the reaction at the same temperature, 0.02 parts of dibutyltin laurate were charged. After the mixture was maintained at the same temperature for 3 hours, 91.7 parts of polycaprolactone-modified hydroxyethyl acrylate (PLACCEL FA5), 0.02 parts of dibutyltin laurate, and 0.02 parts of hydroquinone monomethyl ether were charged. The mixture was maintained at 70° C. for 3 hours to complete the reaction, and 76.5 parts of toluene were added to obtain a urethane acrylate containing 50% by weight of solid.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US06825243B2
출처 데이터셋uspto-grants-2004_11
ORD IDord-17ebe6446b3942bdafa6a6bbfa6ea1a3
출처 메모uspto-grants-2004_11