4-Mercaptophenol → Ethyl(4-bromophenyl)[(4-hydroxyphenyl)sulfanyl]acetate

HRID 2417274노트

반응식

Br[CH:2]([C:8]1[CH:13]=[CH:12][C:11]([Br:14])=[CH:10][CH:9]=1)[C:3]([O:5][CH2:6][CH3:7])=[O:4].[SH:15][C:16]1[CH:21]=[CH:20][C:19]([OH:22])=[CH:18][CH:17]=1>>[CH2:6]([O:5][C:3](=[O:4])[CH:2]([C:8]1[CH:13]=[CH:12][C:11]([Br:14])=[CH:10][CH:9]=1)[S:15][C:16]1[CH:21]=[CH:20][C:19]([OH:22])=[CH:18][CH:17]=1)[CH3:7]

참가 물질

반응물 2

HCID 2401474-Mercaptophenol

HCID 12754876Ethyl 2-bromo-(4-bromophenyl)acetate

생성물 1

HCID 91031423Ethyl(4-bromophenyl)[(4-hydroxyphenyl)sulfanyl]acetate수율 92%

실험 절차

Ethyl(4-bromophenyl)[(4-hydroxyphenyl)sulfanyl]acetate was prepared according to the general method as outlined in example 1 (step 1), starting from ethyl bromo(4-bromophenyl)acetate (15 g, 45.6 mmol) and 4-mercaptophenol (5.75 g, 45.6 mmol); 15.39 g white solid. mp: 55.6° C.; Yield 92%; MS: 365.1 (M−H)−

출처 및 근거

ORD 기록: ord-0f5a2601cacd49a390f5b5020ccab32d
출처 데이터셋: uspto-grants-2004_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US06825354B2

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