2-isopropylidene-1-indanone → HCID 12220946, 화합물

HRID 2419981노트

반응식

HRID 2419981 반응식
[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH:6]1[C:15]2[C:10](=[CH:11][CH:12]=[CH:13][CH:14]=2)[CH2:9][CH2:8][NH+:7]=1.[C:16](=[C:19]1[CH2:27][C:26]2[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=2)[C:20]1=O)([CH3:18])[CH3:17]>CO>[Cl:1]([O-:5])(=[O:4])(=[O:3])=[O:2].[CH3:18][C:16]1[C:19]2[CH2:27][C:26]3[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=3)[C:20]=2[N+:7]2[CH2:8][CH2:9][C:10]3[CH:11]=[CH:12][CH:13]=[CH:14][C:15]=3[C:6]=2[CH:17]=1

참가 물질

4

반응물 2

HCID 15133342-isopropylidene-1-indanoneHCID 20312280HCID 20312280, 화합물

생성물 1

HCID 12220946HCID 12220946, 화합물

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

3,4-Dihydroisoquinolinium perchlorate (2 g) and 2-isopropylidene-indan-1-one (2 g) were heated together at 150° for 2 hours. The reaction mixture was cooled and diluted with methanol. The product was collected by filtration and recrystallized from methanol.

후처리

  1. temperatureThe reaction mixture was cooled
  2. filtrationThe product was collected by filtration
  3. customrecrystallized from methanol

출처 및 근거

ORD 기록
ord-cc4c5aaa884f4b46b3e02b6dab696124
출처 데이터셋
uspto-grants-1978_08
특허 번호
US04108667

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