3-Nitrobenzoic acid → N-(3-methoxyphenyl)-3-nitrobenzamide

반응식

[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([NH2:9])[CH:4]=1.[N+:10]([C:13]1[CH:14]=[C:15]([CH:19]=[CH:20][CH:21]=1)[C:16](O)=[O:17])([O-:12])=[O:11]>>[N+:10]([C:13]1[CH:14]=[C:15]([CH:19]=[CH:20][CH:21]=1)[C:16]([NH:9][C:5]1[CH:6]=[CH:7][CH:8]=[C:3]([O:2][CH3:1])[CH:4]=1)=[O:17])([O-:12])=[O:11]

참가 물질

반응물 2

HCID 84973-Nitrobenzoic acid

HCID 108243-Methoxyaniline

생성물 1

HCID 306640N-(3-methoxyphenyl)-3-nitrobenzamide수율 91.3%

실험 절차

Using m-anisidine (2.03 g, 16.5 mmol) and 3-nitrobenzoic acid (2.51 g, 15.0 mmol), the procedure of Reference Example 16 was repeated to obtain 3.72 g (91.3%) of the title compound in the form of colorless powder.

출처 및 근거

ORD 기록: ord-328ffea84e8945bab5f2c5c05d92ed2e
출처 데이터셋: uspto-grants-1998_03
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US05728835

반응 노트

불러오는 중…