Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Potassium Cyanide → Ethyldiisopropyl-ammonium
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Potassium Cyanide | HCID 9032 | — |
| 반응물 | Diisopropylethylamine | HCID 81531 | — |
| 반응물 | 4-Methylene-3-oxabicyclo[3.2.1]octan-2-one | HCID 12993977 | — |
| 용매 | Acetonitrile | HCID 6342 | — |
| 생성물 | Ethyldiisopropyl-ammonium | HCID 3411517 | — |
| 생성물 | 4-Hydroxybicyclo[3.2.1]oct-3-en-2-one | HCID 12993980 | — |
반응 단계
Analogously to Example P1, 1.38 g (10 mmol) of 4-methylene-3-oxabicyclo[3.2.1]octan-2-one are stirred over a period of 12 hours in the presence of 1.29 g (10 mmol) of Hünig's base and 0.13 g of potassium cyanide in 10 ml of acetonitrile. Solid components (potassium salts) are filtered off and the filtrate is evaporated to dryness to yield the ethyldiisopropyl-ammonium salt of 4-hydroxybicyclo[3.2.1]oct-3-en-2-one in the form of a resin.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06855831B2 |
| 출처 데이터셋 | uspto-grants-2005_02 |
| ORD ID | ord-db5741c94adc43d09fa3ea6ec262eab3 |
| 출처 메모 | uspto-grants-2005_02 |