HCID 54471129, 화합물 → HCID 10856924, 화합물

HRID 247688노트

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HRID 247688 반응식
[CH2:1]1[CH2:16][O:15][CH:3]([CH2:4][CH:5]=[CH:6][C:7]2[CH:14]=[CH:13][C:10]([C:11]#[N:12])=[CH:9][CH:8]=2)[O:2]1>C1(C)C=CC=CC=1.[Pd]>[CH2:16]1[CH2:1][O:2][CH:3]([CH2:4][CH2:5][CH2:6][C:7]2[CH:14]=[CH:13][C:10]([C:11]#[N:12])=[CH:9][CH:8]=2)[O:15]1

참가 물질

4

반응물 1

HCID 54471129HCID 54471129, 화합물

생성물 1

HCID 10856924HCID 10856924, 화합물수율 82%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 1140Toluene용매

실험 절차

A solution of 3.7 g of p-(4,4-ethylenedioxy-1-butenyl)benzonitrile in 50 ml of toluene was treated with 350 mg of palladium/carbon (5%) and the mixture was hydrogenated for 2.5 hours (hydrogen consumption 385 ml). The reaction mixture was then filtered (rinsing with diethyl ether) and the filtrate was evaporated. There were obtained 308 mg (82%) of p-(4,4-ethylenedioxybutyl)benzonitrile as a colourless, partially crystallizing oil.

후처리

  1. custom(hydrogen consumption 385 ml)
  2. filtrationThe reaction mixture was then filtered
  3. wash(rinsing with diethyl ether)
  4. customthe filtrate was evaporated

출처 및 근거

ORD 기록
ord-fedc1941dc2744b9bc49bd9715bc2184
출처 데이터셋
uspto-grants-1987_11
특허 번호
US04709030

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