Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Acetic Anhydride → (3-chlorophenyl)methyl Acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Acetic Anhydride | HCID 7918 | — |
| 반응물 | 3-Chlorobenzyl alcohol | HCID 70117 | — |
| 용매 | Benzene | HCID 241 | — |
| 생성물 | (3-chlorophenyl)methyl Acetate | HCID 11217649 | 96% |
반응 단계
Into a solution of 84.4 g. (0.592 mole) of 3-chlorobenzyl alcohol in 40 cm3. of benzene 61.5 g. (0.6 mole) of acetic acid anhydride are dropped during 15 minutes while boiling. The reaction mixture is refluxed with 100 cm3. of benzene and washed with 100 cm3. of water thoroughly. The organic phase is separated and evaporated. 105.2 g. of 3-chlorobenzyl acetate are obtained which is suitable to ether-formation. nD20 : 1.5226, yield 96%.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04709081 |
| 출처 데이터셋 | uspto-grants-1987_11 |
| ORD ID | ord-0454e46b42c644bf8206535480ccf04b |
| 출처 메모 | uspto-grants-1987_11 |