Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Difluoromethane → CFC-114a HCFC-22
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Difluoromethane | HCID 6345 | — |
| 반응물 | Chlorodifluoromethane | HCID 6372 | — |
| 반응물 | 1,1-Dichloro-1,2,2,2-tetrafluoroethane | HCID 9775 | — |
| 반응물 | 1,1,1,2-Tetrafluoroethane | HCID 13129 | — |
| 반응물 | Hcfc 124 | HCID 17822 | — |
| 생성물 | CFC-114a HCFC-22 | HCID 86734398 | — |
반응 단계
Mixtures of CFC-114a, HCFC-22 and hydrogen were fed to a reactor operated at several temperatures for 40 hours. For a 10.5 hour period at 600° C., at an average time in synthesis of 14 hours, with liquid feed rates of 5.5 mL/hr of CFC-114a and 1 mL/hr of HCFC-22, a hydrogen feed rate of 250 cc/min (1 atm. and room temperature basis); a molar ratio of hydrogen to (HFC-114 at HCFC-22) of 10:1 was provided, and the organic component of the reactor effluent contained an average (area percent) of 51.6% HFC-134a, 35.6% HCFC-124, 0.22% CFC-114a, 4.1% HFC-32 and 5.4% HCFC-22.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05208397 |
| 출처 데이터셋 | uspto-grants-1993_05 |
| ORD ID | ord-3023418b151e4a4db9b5cf9b37d50855 |
| 출처 메모 | uspto-grants-1993_05 |