tert-Butyl hydroperoxide → t-Amylperoxy 2,4-dimethylphenyl carbonate

반응식

[C:1]([O:6][OH:7])([CH2:4][CH3:5])([CH3:3])[CH3:2].Cl[C:9]([O:11][C:12]1[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][C:13]=1[CH3:19])=[O:10].C([O:24]O)(C)(C)C.ClC(OC1C=CC=CC=1)=O>>[C:9](=[O:24])([O:11][C:12]1[CH:17]=[CH:16][C:15]([CH3:18])=[CH:14][C:13]=1[CH3:19])[O:10][O:7][O:6][C:1]([CH2:4][CH3:5])([CH3:3])[CH3:2]

참가 물질

반응물 4

HCID 6410tert-Butyl hydroperoxide

HCID 15891Phenyl chloroformate

HCID 76962tert-Amyl hydroperoxide

HCID 159175932,4-Dimethylphenyl chloroformate

생성물 1

HCID 54014625t-Amylperoxy 2,4-dimethylphenyl carbonate수율 65%

실험 절차

A reaction was carried out in the same manner as described in Example 1, except that t-amyl hydroperoxide and 2,4-dimethylphenyl chloroformate were used in place of t-butyl hydroperoxide and phenyl chloroformate used in Example 1, to obtain 35.7 g (yield: 65%) of a compound having a GLC purity of 92%, which was a colorless liquid at room temperature.