3-(2-Methylpropenyl)benzonitrile → 3-Isobutylbenzonitrile

HRID 249139

반응식

HRID 249139 반응식
[CH3:1][C:2]([CH3:12])=[CH:3][C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[C:7]#[N:8]>CO.[Pd]>[CH2:3]([C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[C:7]#[N:8])[CH:2]([CH3:12])[CH3:1]

참가 물질

4

반응물 1

HCID 190247923-(2-Methylpropenyl)benzonitrile

생성물 1

HCID 190247553-Isobutylbenzonitrile수율 94%

시약·촉매·용매 2

HCID 23938Palladium촉매HCID 887Methanol용매

반응 조건

온도
25 °C

실험 절차

To a solution of 3-(2-methyl-1-propenyl)benzonitrile (5.80 g) in methanol (50 ml) was added 10% palladium on activated carbon (1 g), and the mixture was stirred under hydrogen atmosphere (3 atm) at 25° C. for 1 hour. The catalyst was filtered off and the filtrate was evaporated to give 3-isobutylbenzonitrile (5.52 g) as a pale yellow oil.

후처리

  1. filtrationThe catalyst was filtered off
  2. customthe filtrate was evaporated

출처 및 근거

ORD 기록
ord-d6481656cfa043db90ae1011ec48aef2
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05212320

연결된 노트

불러오는 중…