(-)-(2S,3R)-1-propionyloxy-2,3-epoxy-8-methylnonane → (-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol

HRID 249237노트

반응식

HRID 249237 반응식
C([O:5][CH2:6][C@@H:7]1[O:16][C@@H:8]1[CH2:9][CH2:10][CH2:11][CH2:12][CH:13]([CH3:15])[CH3:14])(=O)CC.[OH-].[K+].CO>>[O:16]1[C@H:8]([CH2:9][CH2:10][CH2:11][CH2:12][CH:13]([CH3:15])[CH3:14])[C@@H:7]1[CH2:6][OH:5]

참가 물질

3

반응물 2

HCID 14102164(-)-(2S,3R)-1-propionyloxy-2,3-epoxy-8-methylnonaneHCID 23689386Potassium hydroxide methanol

생성물 1

HCID 14102158(-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol수율 93.6%

실험 절차

3.4 g of (-)-(2S,3R)-1-propionyloxy-2,3-epoxy-8-methylnonane was hydrolyzed with potassium hydroxide/methanol to yield 2.4 g of (-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol.

출처 및 근거

ORD 기록
ord-f091f1539f854af4b358ec85ba1ccf23
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05213975

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