(-)-(2S,3R)-1-butyroxy-2,3-epoxy-8-methylnonane → (-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol

HRID 249238노트

반응식

HRID 249238 반응식
C([O:6][CH2:7][C@@H:8]1[O:17][C@@H:9]1[CH2:10][CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])(=O)CCC.[OH-].[K+].CO>>[O:17]1[C@H:9]([CH2:10][CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])[C@@H:8]1[CH2:7][OH:6]

참가 물질

3

반응물 2

HCID 18651942(-)-(2S,3R)-1-butyroxy-2,3-epoxy-8-methylnonaneHCID 23689386Potassium hydroxide methanol

생성물 1

HCID 14102158(-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol수율 93.8%

실험 절차

3.6 g of (-)-(2S,3R)-1-butyroxy-2,3-epoxy-8-methylnonane was hydrolyzed with potassium hydroxide/methanol to yield 2.4 g of (-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol.

출처 및 근거

ORD 기록
ord-4176ab5b2d544d5ebf274ed33664a499
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05213975

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