(-)-(2S, 3R)-1-valeroxy-2,3-epoxy-8-methylnonane → (-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol

HRID 249239노트

반응식

HRID 249239 반응식
C([O:7][CH2:8][C@@H:9]1[O:18][C@@H:10]1[CH2:11][CH2:12][CH2:13][CH2:14][CH:15]([CH3:17])[CH3:16])(=O)CCCC.[OH-].[K+].CO>>[O:18]1[C@H:10]([CH2:11][CH2:12][CH2:13][CH2:14][CH:15]([CH3:17])[CH3:16])[C@@H:9]1[CH2:8][OH:7]

참가 물질

3

반응물 2

HCID 18651943(-)-(2S, 3R)-1-valeroxy-2,3-epoxy-8-methylnonaneHCID 23689386Potassium hydroxide methanol

생성물 1

HCID 14102158(-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol수율 90.1%

실험 절차

3.8 g of (-)-(2S, 3R)-1-valeroxy-2,3-epoxy-8-methylnonane was hydrolyzed with potassium hydroxide/methanol to yield 2.3 g of (-)-(2S, 3R)-2,3-epoxy-8-methyl-1-nonanol.

출처 및 근거

ORD 기록
ord-97ca31a3879f4fb5b8a546d2a6c7b1d6
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05213975

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