Potassium hydroxide methanol → (-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol

HRID 249240노트

반응식

HRID 249240 반응식
C([O:10][CH2:11][C@@H:12]1[O:21][C@@H:13]1[CH2:14][CH2:15][CH2:16][CH2:17][CH:18]([CH3:20])[CH3:19])(=O)CCCCCCC.[OH-].[K+].CO>>[O:21]1[C@H:13]([CH2:14][CH2:15][CH2:16][CH2:17][CH:18]([CH3:20])[CH3:19])[C@@H:12]1[CH2:11][OH:10]

참가 물질

3

반응물 2

HCID 23689386Potassium hydroxide methanolHCID 86746866(-)-(2S, 3R)-1-capryloxy-2,3-epoxy-8-methylnonane

생성물 1

HCID 14102158(-)-(2S,3R)-2,3-epoxy-8-methyl-1-nonanol수율 97.2%

실험 절차

4.1 g of (-)-(2S, 3R)-1-capryloxy-2,3-epoxy-8-methylnonane was hydrolyzed with potassium hydroxide/methanol to yield 2.3 g of (-)-(2S, 3R)-2,3-epoxy-8-methyl-1-nonanol.

출처 및 근거

ORD 기록
ord-690be5e88e4148e1bd15b2bfe09f3920
출처 데이터셋
uspto-grants-1993_05
특허 번호
US05213975

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