참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Resorcinol | HCID 5054 | — |
| 반응물 | 1-Bromoadamantane | HCID 79106 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | 4,6-Bis(adamantyl)resorcinol | HCID 23555834 | 69.9% |
반응 단계
In a 300 mL recovery flask, 75.0 g of 1-bromoadamantane (349 mmol), 9.58 g of 1,3-dihydroxybenzene (87.0 mmol), 25 mL of toluene and a stirrer were charged and agitated at 130° C. for 24 hours under nitrogen flow. Solvent was removed therefrom under reduced pressure to obtain solid. The solid was purified by column chromatography, thus obtaining 23.0 g of 4,6-di(1-adamantyl)-1,3-dihydroxybenzene (60.8 mmol; yield: 69.9%).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US07863347B2 |
|---|
| 출처 데이터셋 | uspto-grants-2011_01 |
|---|
| ORD ID | ord-5bab8949d64846f3b9204a88c0a5e37d |
|---|
| 출처 메모 | uspto-grants-2011_01 |
|---|
