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Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 252896생성일: 2026년 10월 26일

Ammonia → Silicon tetramethoxide

https://huagongshe.com/reaction/252896

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참여 물질

역할이름HCID투입량
반응물AmmoniaHCID 222—
반응물MethanolHCID 887—
반응물TetramethoxysilaneHCID 12682—
용매IsopropanolHCID 3776—
생성물Silicon tetramethoxideHCID 21871620—

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온도40 °C

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The fine particles used were composite inorganic fine particles of silica and titania (average particle diameter: 100 nm). The fine particles were produced in the following manner according to the method disclosed in Production Example and Example of JP-A-7-2520. 140 g of methanol, 260 g of isopropanol and 100 g of aqueous ammonia (25% by weight) were charged in a 4-L glass reactor equipped with stirring blades to prepare a reaction solution, which was stirred while the temperature of the reaction solution was maintained to 40° C. 542 g of silicon tetramethoxide (Si(OMe)4, Methyl Silicate 39, a trade name, produced by Colcoat Co., Ltd.) was charged in a 3-L conical flask, and 195 g of methanol and 28 g of a 0.1% by weight aqueous solution of hydrochloric acid (obtained by diluting 35% hydrochloric acid, produced by Wako Pure Chemical Industries, Ltd. with water to 1/1,000) were added thereto under stirring, followed by further stirring for about 10 minutes. Subsequently, a solution obtained by diluting 300 g of titanium tetraisopropoxide (Ti(O-i-Pr)4, A-1 (TPT), a trade name, produced by Nippon Soda Co., Ltd.) with 634 g of isopropanol was added thereto to obtain a transparent uniform solution (copolycondensate of silicon tetraalkoxide and titanium tetraalkoxide). 1,699 g of the uniform solution and 480 g of aqueous ammonia (25% by weight) were simultaneously added dropwise to the aforementioned reaction solution over 2 hours at a small dropping rate in the initial stage, which was gradually increased toward the final stage. After completing the dropwise addition, the resulting cohydrolyzate was filtered and dried at 50° C. to remove the organic solvents, and it was then dispersed in water to obtain fine particles having a concentration of 10% by weight and a refractive index of 1.56.

출처 및 근거

DOI10.6084/m9.figshare.5104873.v1
특허 번호US07871691B2
출처 데이터셋uspto-grants-2011_01
ORD IDord-0f015da9bd7a4e66925f6f836b01ca75
출처 메모uspto-grants-2011_01