Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Oxalyl chloride → Hexahydro-2,5-methano-pentalene-3a-carbonyl chloride
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Oxalyl chloride | HCID 65578 | — |
| 반응물 | Hexahydro-2,5-methanopentalene-3a(1H)-carboxylic acid | HCID 2733865 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Hexahydro-2,5-methano-pentalene-3a-carbonyl chloride | HCID 13182402 | 99.3% |
반응 단계
To a solution of commercially available hexahydro-2,5-methano-pentalene-3a-carboxylic acid (10 g, 0.06 mol) in dichloromethane (200 mL) was added oxalyl chloride (8.7 g, 0.066 mol). The mixture was stirred overnight and then concentrated under reduced pressure to afford the title compound as a colorless oil (11 g, 99%). MS (DCI/NH3) m/z 184 (M+H)+.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07875639B2 |
| 출처 데이터셋 | uspto-grants-2011_01 |
| ORD ID | ord-82faefc782d147d88966d283fa9acab9 |
| 출처 메모 | uspto-grants-2011_01 |