1-Chloroanthraquinone → 1-Butylphenylamino anthraquinone

HRID 256278

반응식

HRID 256278 반응식
Cl[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][CH:3]=1.C([NH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)CCC.C([O-])(=O)C.[Na+].[N+]([C:37]1[CH:42]=CC=[CH:39][CH:38]=1)([O-])=O>C([O-])(=O)C.[Cu+2].C([O-])(=O)C>[CH2:42]([C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[CH:5]=[CH:4][C:3]=1[NH:22][C:23]1[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=1)[CH2:37][CH2:38][CH3:39]

참가 물질

6

반응물 4

HCID 67091-ChloroanthraquinoneHCID 7416NitrobenzeneHCID 14310N-Butylaniline2회HCID 517045Sodium Acetate

생성물 1

HCID 704309131-Butylphenylamino anthraquinone

시약·촉매·용매 1

HCID 8895Cupric acetate촉매

실험 절차

The pleochroic dye 1-butylphenylamino anthraquinone was prepared by dissolving 1-chloroanthraquinone in a 10-fold excess of 4-n butylaniline. Copper acetate and sodium acetate were added as in Example 70. Since the n-butylaniline is a solvent in this case no nitrobenzene was added. The dye, when tested as in Example 70, had an absorption maxima at 515 nm and an order parameter of 0.65.

후처리

  1. additionwas added

출처 및 근거

ORD 기록
ord-ca152b54d7c748e2af8679ae4be944b8
출처 데이터셋
uspto-grants-1987_10
특허 번호
US04702561

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