2-Vinylnaphthalene → Chloromethylstyrene 2-vinylnaphthalene

HRID 256302

반응식

HRID 256302 반응식
[Cl:1][CH2:2][CH:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[CH:11]([C:13]1[CH:22]=[CH:21][C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=1)=[CH2:12]>>[Cl:1][CH2:2][CH:3]=[CH:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[CH:11]([C:13]1[CH:22]=[CH:21][C:20]2[C:15](=[CH:16][CH:17]=[CH:18][CH:19]=2)[CH:14]=1)=[CH2:12]

참가 물질

3

반응물 2

HCID 132302-VinylnaphthaleneHCID 94242Benzene, (3-chloro-1-propenyl)-

생성물 1

HCID 86741842Chloromethylstyrene 2-vinylnaphthalene수율 100%

실험 절차

Four different polymer particles were prepared containing different proportions of monomers in the shell as shown in Table 7. Each preparation began with 50 mL of latex from Example 6A and 1 g of a mixture of chloromethylstyrene and 2-vinylnaphthalene in the appropriate ratio to produce 10, 30, 70, and 100 percent (w/w) chloromethylstyrene/2-vinylnaphthalene shells (lots 6.1, 6.2, 6.3, and 6.4, respectively, the latex from Example 6A having been designated as 6.0). For each preparation, 50 mg of potassium persulfate was used in one-hour polymerizations at 95°-100° C. The monomer conversions and optical densities at 340 nm of a 1:100 dilution in water of the polymer particle latices are also shown in Table 7; the solids content was 14%

후처리

  1. customFour different polymer particles were prepared
  2. additioncontaining different proportions of monomers in the shell

출처 및 근거

ORD 기록
ord-e12cda8011ba4184a4503d9d6ef88736
출처 데이터셋
uspto-grants-1987_10
특허 번호
US04703018

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